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Figure 9.4 Energy-Yielding Metabolic Pathways Energy-yielding reactions can be grouped into five metabolic pathways: glycolysis, pyruvate oxidation, the citric acid cycle, the respiratory chain/ATP synthesis, and fermentation. (A) The three lower pathways occur only in the presence of O2 and are collectively referred to as cellular respiration. (B) When O2 is unavailable, glycolysis is followed by fermentation.